What are the targeting settings for your command?
Pressing Enter (physically or otherwise) does not open the "Edit a Profile" window on my machine; It can open the "Edit a Command" window if you press enter while the log and specifically a log entry for executing or stopping a command has focus, but I don't see that window in your screenshot.
Alt-E does open the "Edit a Profile" window (it is the assigned UI shortcut for that, but again, only providing VoiceAttack has focus)